We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.
Y. D. Bidal, M. Lesieur, M. Melaimi, D. B. Cordes, A. M. Z. Slawin, G. Bertrand and C. S. J. Cazin, Chem. Commun., 2015, 51, 4778 DOI: 10.1039/C4CC10375K
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