Issue 18, 2015
From the journal:

Chemical Communications

enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes†

Nidal Saleh,a   Monika Srebro,b   Thibault Reynaldo,a   Nicolas Vanthuyne,c   Loïc Toupet,a   Victoria Y. Chang,d   Gilles Muller,d   J. A. Gareth Williams,e   Christian Roussel,c   Jochen Autschbach*f  and  Jeanne Crassous*a  

* Corresponding authors

a Institut des Sciences Chimiques de Rennes, UMR 6226, Institut de Physique de Rennes, UMR 6251, Campus de Beaulieu, CNRS-Université de Rennes 1, 35042 Rennes Cedex, France
E-mail: jeanne.crassous@univ-rennes1.fr

b Faculty of Chemistry, Jagiellonian University, 30-060 Krakow, Poland

c Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, Marseille, France

d Department of Chemistry, San José State University, San José, CA 95192-0101, USA

e Department of Chemistry, University of Durham, Durham, DH1 3LE, UK

f Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA
E-mail: jochena@buffalo.edu

Abstract

The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.

Graphical abstract: enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes

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Article information

DOI
https://doi.org/10.1039/C5CC00453E
Article type
Communication
Submitted
16 Jan 2015
Accepted
22 Jan 2015
First published
23 Jan 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 3754-3757

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enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes

N. Saleh, M. Srebro, T. Reynaldo, N. Vanthuyne, L. Toupet, V. Y. Chang, G. Muller, J. A. G. Williams, C. Roussel, J. Autschbach and J. Crassous, Chem. Commun., 2015, 51, 3754 DOI: 10.1039/C5CC00453E

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