Issue 23, 2015
From the journal:

Chemical Communications

Planar-chiral building blocks for metal–organic frameworks†

Murat Cakici,‡ab   Zhi-Gang Gu,‡c   Martin Nieger,d   Jochen Bürck,e   Lars Heinke*c  and  Stefan Bräse*af  

* Corresponding authors

a Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany
E-mail: braese@kit.edu

b Faculty of Sciences, Department of Chemistry, Ataturk University, 25240 Erzurum, Turkey

c Institut für Funktionelle Grenzflächen (IFG), Karlsruher Institut für Technologie (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
E-mail: Lars.Heinke@kit.edu

d Laboratory of Inorganic Chemistry, University of Helsinki, P.O. Box 55, Fi-00014 Helsinki, Finland
E-mail: martin.nieger@helsinki.fi

e Institute of Biological Interfaces 2 (IBG 2), Karlsruhe Institute of Technology (KIT), P.O. Box 3640, 76021 Karlsruhe, Germany

f Institute of Toxicology and Genetics, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

The first example of a planar-chiral building block being used for chiral metal–organic frameworks (MOFs) is presented. The porous MOF structure combined with the chiral properties of the planar linker allows a selective adsorption, demonstrated for a nonpolar terpene limonene in thin surface-mounted MOF films.

Graphical abstract: Planar-chiral building blocks for metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C5CC00694E
Article type
Communication
Submitted
24 Jan 2015
Accepted
10 Feb 2015
First published
10 Feb 2015

Chem. Commun., 2015,51, 4796-4798

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Planar-chiral building blocks for metal–organic frameworks

M. Cakici, Z. Gu, M. Nieger, J. Bürck, L. Heinke and S. Bräse, Chem. Commun., 2015, 51, 4796 DOI: 10.1039/C5CC00694E

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