Issue 46, 2015
From the journal:

Chemical Communications

A highly robust metal–organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4†

Hongming He,a   Yang Song,a   Chuanqi Zhang,a   Fuxing Sun,*a   Rongrong Yuan,a   Zheng Bian,*b   Lianxun Gaob  and  Guangshan Zhua  

* Corresponding authors

a State Key laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, China
E-mail: fxsun@jlu.edu.cn
Fax: +86-431-85168331
Tel: +86-431-85168887

b State Key laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: bianzh@ciac.ac.cn
Fax: +86-431-85697831
Tel: +86-431-85262291

Abstract

A highly robust MOF based on a 12-carboxyl dendritic aromatic ligand and two Cd clusters is successfully synthesized. This activated MOF exhibits high heat of absorption of CO2 and highly selective adsorption of CO2 over CH4. Especially, a new type of topology (hhm-a) is presented.

Graphical abstract: A highly robust metal–organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC01281C
Article type
Communication
Submitted
11 Feb 2015
Accepted
28 Apr 2015
First published
28 Apr 2015

Chem. Commun., 2015,51, 9463-9466

Permissions

Request permissions

A highly robust metal–organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4

H. He, Y. Song, C. Zhang, F. Sun, R. Yuan, Z. Bian, L. Gao and G. Zhu, Chem. Commun., 2015, 51, 9463 DOI: 10.1039/C5CC01281C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements