Issue 39, 2015

Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes

Abstract

2,2-Dimethyl-1,3-dioxolane connected to two pyrene moieties through flexible wires in chloroform exhibited cryptochirality in the ground state, as proven by the lack of detectable circular dichroism signals. This cryptochirality was deciphered in the photoexcited state by circularly polarised luminescence signals.

Graphical abstract: Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes

Supplementary files

Article information

Article type
Communication
Submitted
17 Feb 2015
Accepted
20 Mar 2015
First published
20 Mar 2015

Chem. Commun., 2015,51, 8237-8240

Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes

T. Amako, K. Nakabayashi, N. Suzuki, S. Guo, N. A. A. Rahim, T. Harada, M. Fujiki and Y. Imai, Chem. Commun., 2015, 51, 8237 DOI: 10.1039/C5CC01465D

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