Issue 32, 2015

Oxidation with air by ascorbate-driven quinone redox cycling

Abstract

Transition metal-free oxidation with air at room temperature has been achieved by simply using ascorbate (vitamin C) and catalytic amounts of menadione (vitamin K3). A combination of the mentioned vitamins transforms atmospheric oxygen into hydrogen peroxide, which is able to oxidize arylboronic acids and other chemical moieties.

Graphical abstract: Oxidation with air by ascorbate-driven quinone redox cycling

Supplementary files

Article information

Article type
Communication
Submitted
18 Feb 2015
Accepted
19 Mar 2015
First published
19 Mar 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 7027-7030

Author version available

Oxidation with air by ascorbate-driven quinone redox cycling

G. Silveira-Dorta, D. M. Monzón, F. P. Crisóstomo, T. Martín, V. S. Martín and R. Carrillo, Chem. Commun., 2015, 51, 7027 DOI: 10.1039/C5CC01519G

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