Issue 59, 2015
From the journal:

Chemical Communications

Renaissance for low shrinking resins: all-in-one solution by bi-functional vinylcyclopropane-amides†

Paul Pineda Contreras,a   Christian Kuttner,b   Andreas Fery,b   Ullrich Stahlschmidt,c   Valérie Jérôme,c   Ruth Freitagc  and  Seema Agarwal*a  

* Corresponding authors

a Macromolecular Chemistry II and Bayreuth Center for Colloids and Interfaces, Universität Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany
E-mail: agarwal@uni-bayreuth.de
Tel: +49-921-553397

b Physical Chemistry II, Universität Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany

c Process Biotechnology, Universität Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany

Abstract

A low volume shrinking vinylcyclopropane (VCP) monomer, showing both a high reactivity and a low viscosity, was obtained by applying a sterically hindered and isomeric spacer element, incorporating intermolecular amide hydrogen bonds. The resulting properties locate this VCP system in a pronounced range that so far no other efficient and radical polymerizable resin could enter.

Graphical abstract: Renaissance for low shrinking resins: all-in-one solution by bi-functional vinylcyclopropane-amides

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Article information

DOI
https://doi.org/10.1039/C5CC03901K
Article type
Communication
Submitted
11 May 2015
Accepted
16 Jun 2015
First published
16 Jun 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 11899-11902

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Renaissance for low shrinking resins: all-in-one solution by bi-functional vinylcyclopropane-amides

P. Pineda Contreras, C. Kuttner, A. Fery, U. Stahlschmidt, V. Jérôme, R. Freitag and S. Agarwal, Chem. Commun., 2015, 51, 11899 DOI: 10.1039/C5CC03901K

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