Metallopeptoid catalysts incorporating phenanthroline–copper and TEMPO, and at least one non-catalytic group perform in the oxidation of various benzylic, allylic and aliphatic primary alcohols with a TON of up to 16 times higher than a mixture of the two catalytic groups or the peptoid dimer that is lacking the non-catalytic group.
K. J. Prathap and G. Maayan, Chem. Commun., 2015, 51, 11096 DOI: 10.1039/C5CC04266F
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