Issue 73, 2015
From the journal:

Chemical Communications

Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals†

Xiaoqiang Du,a   Yong Ding,*ab   Fangyuan Song,a   Baochun Ma,a   Junwei Zhaoc  and  Jie Songd  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
E-mail: dingyong1@lzu.edu.cn

b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

c Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P. R. China

d Department of Biomedical Engineering, Emory University and Georgia Institute of Technology, Atlanta, Georgia 30322, USA

Abstract

An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 ± 50 and a turn-over frequency (TOFinitial) of 6.3 s−1 over 1 were achieved for water oxidation.

Graphical abstract: Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals

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Article information

DOI
https://doi.org/10.1039/C5CC04551G
Article type
Communication
Submitted
03 Jun 2015
Accepted
21 Jul 2015
First published
21 Jul 2015

Chem. Commun., 2015,51, 13925-13928

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Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals

X. Du, Y. Ding, F. Song, B. Ma, J. Zhao and J. Song, Chem. Commun., 2015, 51, 13925 DOI: 10.1039/C5CC04551G

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