Issue 74, 2015
From the journal:

Chemical Communications

A mild carbon–boron bond formation from diaryliodonium salts†

N. Miralles,a   R. M. Romero,b   E. Fernández*a  and  K. Muñiz*bc  

* Corresponding authors

a Department Química Física i Inorgánica, University Rovira i Virgili, C/Marcellí Domingo s/n, 43007 Tarragona, Spain
E-mail: Mariaelena.fernandez@urv.cat

b Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: kmuniz@ICIQ.ES

c Catalan Institution for Research and Advanced Studies (ICREA), Pg. Lluís Companys 23, 08010 Barcelona, Spain

Abstract

The direct metal-free borylation of diaryliodonium salts with diboron reagents is now demonstrated to be a feasible process toward formation of aryl boronic esters without any additive or catalysts, and it can be extended to a two-step C–C coupling of both aryl groups of the initial diaryliodonium reagent.

Graphical abstract: A mild carbon–boron bond formation from diaryliodonium salts

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC04944J
Article type
Communication
Submitted
16 Jun 2015
Accepted
29 Jul 2015
First published
29 Jul 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 14068-14071

Author version available

Download author version (PDF)

Permissions

Request permissions

A mild carbon–boron bond formation from diaryliodonium salts

N. Miralles, R. M. Romero, E. Fernández and K. Muñiz, Chem. Commun., 2015, 51, 14068 DOI: 10.1039/C5CC04944J

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements