Herein we describe the first example of a ratiometric lanthanide luminescent oxygen sensing interface. Immobilisation of terbium and europium cyclen complexes on glass substrates was achieved by a novel aryl nitrene photografting approach. The resulting interfaces demonstrated a ratiometric oxygen response between 0 and 0.2 atm partial oxygen pressure.
J. Lehr, M. Tropiano, P. D. Beer, S. Faulkner and J. J. Davis, Chem. Commun., 2015, 51, 15944 DOI: 10.1039/C5CC05738H
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