Issue 90, 2015
From the journal:

Chemical Communications

Paddlewheel 1,2,4-diazaphospholide dibismuthanes with very short bismuth–bismuth single bonds†

Minggang Zhao,a   Lixia Wang,a   Pangpang Li,a   Xiang Zhang,a   Ying Yangb  and  Wenjun Zheng*ac  

* Corresponding authors

a Institute of Organic Chemistry & College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province, China
E-mail: wjzheng@sxnu.edu.cn, wjzheng_sxnu@qq.com

b School of Chemistry and Chemical Engineering Central South University, Lushannan Road 932, Changsha, Hunan Province 410083, P. R. China

c Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Gongyuan Street 1, Linfen, Shanxi Province, China

Abstract

One-electron oxidation of the 1,2,4-diazaphospholide anion [3,5-R2dp]− by BiCl3 generated several remarkable paddlewheel dibismuthanes [L2(Bi−Bi)L2] (L = η1,η1-3,5-R2dp, R = tBu, iPr, or Ph) with very short Bi–Bi single bond lengths (2.7964(4)–2.8873(3) Å).

Graphical abstract: Paddlewheel 1,2,4-diazaphospholide dibismuthanes with very short bismuth–bismuth single bonds

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Article information

DOI
https://doi.org/10.1039/C5CC07064C
Article type
Communication
Submitted
22 Aug 2015
Accepted
10 Sep 2015
First published
15 Sep 2015

Chem. Commun., 2015,51, 16184-16187

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Paddlewheel 1,2,4-diazaphospholide dibismuthanes with very short bismuth–bismuth single bonds

M. Zhao, L. Wang, P. Li, X. Zhang, Y. Yang and W. Zheng, Chem. Commun., 2015, 51, 16184 DOI: 10.1039/C5CC07064C

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