Issue 88, 2015
From the journal:

Chemical Communications

Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(i)†

Mark R. Crimmin,*a   Michael J. Butlera  and  Andrew J. P. Whitea  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK
E-mail: m.crimmin@imperial.ac.uk
Tel: +44 (0)2075942846

Abstract

Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C–F or C–O bond to the Al(I) centre.

Graphical abstract: Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(i)

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Article information

DOI
https://doi.org/10.1039/C5CC07140B
Article type
Communication
Submitted
25 Aug 2015
Accepted
14 Sep 2015
First published
14 Sep 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 15994-15996

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Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(I)

M. R. Crimmin, M. J. Butler and A. J. P. White, Chem. Commun., 2015, 51, 15994 DOI: 10.1039/C5CC07140B

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