Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

Hiromitsu Maeda; Ayaka Fukui; Ryohei Yamakado; Nobuhiro Yasuda

doi:10.1039/C5CC07493B

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Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations†

Hiromitsu Maeda,*^a Ayaka Fukui,^a Ryohei Yamakado^a and Nobuhiro Yasuda^b

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* Corresponding authors

^a College of Pharmaceutical Sciences, Ritsumeikan University, Kusatsu 525-8577, Japan
E-mail: maedahir@ph.ritsumei.ac.jp

^b Research and Utilization Division, Japan Synchrotron Radiation Research Institute, Sayo 679-5198, Japan

Abstract

A nitro-substituted dipyrrolylphenol was synthesized as a precursor of a π-electronic anion, whose phenolate (phenoxide) moiety upon deprotonation was stabilized by the hydrogen-bond-donating pyrrole NH, thus forming solid-state ion pairs with various cationic species.

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DOI: https://doi.org/10.1039/C5CC07493B
Article type: Communication
Submitted: 07 Sep 2015
Accepted: 12 Oct 2015
First published: 14 Oct 2015

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Chem. Commun., 2015,51, 17572-17575

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Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

H. Maeda, A. Fukui, R. Yamakado and N. Yasuda, Chem. Commun., 2015, 51, 17572 DOI: 10.1039/C5CC07493B

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Chemical Communications

Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations†

Abstract

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Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

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