Issue 39, 2015
From the journal:

CrystEngComm

Partial rotation of the isopropyl group in the solid state: single-crystal-to-single-crystal phase transformation in a carvacrol derivative†

Umesh D. Pete,a   Amol G. Dikundwar,b   Vaishali M. Sharma,b   Shridhar P. Gejji,c   Ratnamala S. Bendrea  and  Tayur N. Guru Row*b  

* Corresponding authors

a School of Chemical Sciences, North Maharashtra University, Jalgaon, India

b Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India
E-mail: ssctng@sscu.iisc.ernet.in
Fax: +91 80 23601310
Tel: +91 80 23932796

c Department of Chemistry, Savitribai Phule Pune University, Pune, India

Abstract

A hitherto unseen rotation of the isopropyl group in the solid state, predicted to be forbidden based on theoretical investigations, is reported. This C–C rotation observed during the temperature dependent single-crystal-to-single-crystal transformation is attributed to the concomitant changes in molecular structure and intermolecular packing.

Graphical abstract: Partial rotation of the isopropyl group in the solid state: single-crystal-to-single-crystal phase transformation in a carvacrol derivative

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Article information

DOI
https://doi.org/10.1039/C5CE01156F
Article type
Communication
Submitted
14 Jun 2015
Accepted
29 Aug 2015
First published
31 Aug 2015

CrystEngComm, 2015,17, 7482-7485

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Partial rotation of the isopropyl group in the solid state: single-crystal-to-single-crystal phase transformation in a carvacrol derivative

U. D. Pete, A. G. Dikundwar, V. M. Sharma, S. P. Gejji, R. S. Bendre and T. N. Guru Row, CrystEngComm, 2015, 17, 7482 DOI: 10.1039/C5CE01156F

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