Synthesis of an exceptional water-stable two-fold interpenetrated Zn(II)-paddlewheel metal–organic framework

Jingjing Wang; Jun Zhang; Fengyan Jin; Yanping Luo; Shufen Wang; Zaiyong Zhang; Yong Wu; Hongke Liu; Jack Y. Lu; Min Fang

doi:10.1039/C5CE01192B

Synthesis of an exceptional water-stable two-fold interpenetrated Zn(ii)-paddlewheel metal–organic framework†

Jingjing Wang,^ad Jun Zhang,^b Fengyan Jin,^a Yanping Luo,^a Shufen Wang,^a Zaiyong Zhang,^a Yong Wu,*^a Hongke Liu,^ad Jack Y. Lu^c and Min Fang*^ade

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* Corresponding authors

^a Department of Chemistry, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China
E-mail: fangmin@njnu.edu.cn, wuyong@njnu.edu.cn

^b Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei, Anhui 230022, China

^c Department of Chemistry, University of Houston-Clear Lake, 2700 Bay Area Blvd., Houston, TX 77058, USA

^d State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

^e Jiangsu Key Laboratory for NSLSCS, Nanjing Normal Univeristy, Nanjing 210023, China

Abstract

Based on the ligands tetrakis(4-carboxyphenyl)silane (TCS) and 4,4′-bipy, a novel 3D doubly interpenetrated Zn(II)-paddlewheel metal–organic framework Zn₂TCS(4,4′-bipy) (1) was synthesized via facile conversion of its non-interpenetrated isomer (2) upon solvent removal at ambient temperature. It exhibits high CO₂ and CH₄ adsorption capacities and exceptional water stability.

CrystEngComm

Synthesis of an exceptional water-stable two-fold interpenetrated Zn(ii)-paddlewheel metal–organic framework†

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Synthesis of an exceptional water-stable two-fold interpenetrated Zn(II)-paddlewheel metal–organic framework

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