Issue 1, 2015

Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

Abstract

A moisture-tolerant cyclopentadienyl–silsesquioxane titanium complex efficiently catalyses the selective oxidation of various types of sulfides to either sulfoxides (TOFs up to 32 530 h−1) or sulfones with H2O2 (30% in water) under mild conditions.

Graphical abstract: Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

Supplementary files

Article information

Article type
Paper
Submitted
25 Jul 2014
Accepted
20 Aug 2014
First published
21 Aug 2014

Catal. Sci. Technol., 2015,5, 320-324

Author version available

Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

L. Postigo, M. Ventura, T. Cuenca, G. Jiménez and B. Royo, Catal. Sci. Technol., 2015, 5, 320 DOI: 10.1039/C4CY00965G

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