Catalytic dehydrofluorination of 1,1,1,2-tetrafluoroethane to synthesize trifluoroethylene over a modified NiO/Al2O3 catalyst

Wenzhi Jia; Min Liu; Xuewei Lang; Chao Hu; Junhui Li; Zhirong Zhu

doi:10.1039/C5CY00211G

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Catalytic dehydrofluorination of 1,1,1,2-tetrafluoroethane to synthesize trifluoroethylene over a modified NiO/Al₂O₃ catalyst†

Wenzhi Jia,^a Min Liu,^a Xuewei Lang,^a Chao Hu,^a Junhui Li^a and Zhirong Zhu*^a

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* Corresponding authors

^a Department of Chemistry, Tongji University, Shanghai 200092, China
E-mail: zhuzhirong@tongji.edu.cn
Fax: (+86) 21 65982563

Abstract

A promising fluorinated NiO/Al₂O₃ catalyst for synthesizing trifluoroethylene through the catalytic dehydrofluorination of CF₃CFH₂ was prepared, and the relationship between the Lewis acid sites and activity was investigated. 20.1% conversion of CF₃CFH₂ was observed, and the selectivity to trifluoroethylene was observed to be 99% at 430 °C after 100 h.

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Article information

DOI: https://doi.org/10.1039/C5CY00211G
Article type: Communication
Submitted: 08 Feb 2015
Accepted: 30 Mar 2015
First published: 31 Mar 2015

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Catal. Sci. Technol., 2015,5, 3103-3107

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Catalytic dehydrofluorination of 1,1,1,2-tetrafluoroethane to synthesize trifluoroethylene over a modified NiO/Al₂O₃ catalyst

W. Jia, M. Liu, X. Lang, C. Hu, J. Li and Z. Zhu, Catal. Sci. Technol., 2015, 5, 3103 DOI: 10.1039/C5CY00211G

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