Issue 7, 2015

Second-sphere coordination-induced morphology transformation from phosphorescent nanowires to microcubes

Abstract

Nanowires of a pyridyl-functionalized iridium complex are transformed into microcubes as a result of hydrogen-bond-assisted second-sphere coordination between pyridyl groups and monovalent anions of 1,3,5-benzenetricarboxylic acid (H2BTC). This is accompanied by a blue-shift of the phosphorescence from 662 to 638 nm.

Graphical abstract: Second-sphere coordination-induced morphology transformation from phosphorescent nanowires to microcubes

Supplementary files

Article information

Article type
Communication
Submitted
03 Mar 2014
Accepted
08 Jan 2015
First published
08 Jan 2015

Dalton Trans., 2015,44, 2970-2972

Second-sphere coordination-induced morphology transformation from phosphorescent nanowires to microcubes

F. Xue, Y. Ma, Z. Zhou, L. Qin, Y. Lu, H. Yang and S. Yang, Dalton Trans., 2015, 44, 2970 DOI: 10.1039/C4DT00640B

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