BaMn9II(VO4)6(OH)2: a homospin ferrimagnet with a broken spinel-lattice of B-sites

Wenbin Guo; Zhangzhen He; Yingying Tang; Suyun Zhang; Ming Yang; Wendan Cheng

doi:10.1039/C4DT02930E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

BaMn₉^II(VO₄)₆(OH)₂: a homospin ferrimagnet with a broken spinel-lattice of B-sites†

Wenbin Guo,^a Zhangzhen He,*^a Yingying Tang,^ab Suyun Zhang,^a Ming Yang^a and Wendan Cheng^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
E-mail: hezz@fjirsm.ac.cn

^b Graduate School of the Chinese Academy of Sciences, Beijing, P. R. China

Abstract

A new vanadate of BaMn₉^II(VO₄)₆(OH)₂ was synthesized by a conventional hydrothermal method. BaMn₉^II(VO₄)₆(OH)₂ crystallizes in the cubic space group Pa [3 with combining macron] , which exhibits an edge-sharing MnO₆ octahedral network structure with cavities occupied by Ba(VO₄)₆¹⁶⁻ groups. The lattice built by Mn²⁺ ions shows the reverse triangular dipyramid Mn₇ in the system, which can be considered as a broken spin lattice of B-sites in spinels. The title compound shows a ferrimagnetic behavior with T_C = 18 K.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C4DT02930E
Article type: Paper
Submitted: 23 Sep 2014
Accepted: 23 Oct 2014
First published: 24 Oct 2014

Download Citation

Dalton Trans., 2015,44, 6363-6367

Permissions

Request permissions

BaMn₉^II(VO₄)₆(OH)₂: a homospin ferrimagnet with a broken spinel-lattice of B-sites

W. Guo, Z. He, Y. Tang, S. Zhang, M. Yang and W. Cheng, Dalton Trans., 2015, 44, 6363 DOI: 10.1039/C4DT02930E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions