Issue 7, 2015
From the journal:

Dalton Transactions

Single ion magnet behaviour in a two-dimensional network of dicyanamide-bridged cobalt(ii) ions†

Joanna Palion-Gazda,a   Tomasz Klemens,a   Barbara Machura,*a   Julia Vallejo,b   Francesc Lloretb  and  Miguel Julve*b  

* Corresponding authors

a Department of Crystallography, Institute of Chemistry, University of Silesia, 9th Szkolna St, 40006 Katowice, Poland
E-mail: basia@ich.us.edu.pl

b Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Facultat de Química de la Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain
E-mail: miguel.julve@uv.es

Abstract

A novel two-dimensional coordination polymer of the formula [Co(dca)2(atz)2]n (1) resulted from assembling trans-bis(2-amino-1,3,5-triazine)cobalt(II) motifs by dicyanamide spacers. Variable-temperature dc and ac magnetic susceptibility measurements of 1 show that the high-spin cobalt(II) ions act as single ion magnets (SIMs).

Graphical abstract: Single ion magnet behaviour in a two-dimensional network of dicyanamide-bridged cobalt(ii) ions

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Article information

DOI
https://doi.org/10.1039/C4DT03574G
Article type
Communication
Submitted
20 Nov 2014
Accepted
07 Jan 2015
First published
07 Jan 2015
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2015,44, 2989-2992

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Single ion magnet behaviour in a two-dimensional network of dicyanamide-bridged cobalt(II) ions

J. Palion-Gazda, T. Klemens, B. Machura, J. Vallejo, F. Lloret and M. Julve, Dalton Trans., 2015, 44, 2989 DOI: 10.1039/C4DT03574G

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