Issue 4, 2015
From the journal:

Dalton Transactions

Metal-induced B–H bond activation: reactions between half-sandwich Ir and Rh complexes with carboranylthioamide†

Bin Xu,a   Yin-Ping Wang,a   Zi-Jian Yaoa  and  Guo-Xin Jin*a  

* Corresponding authors

a Shanghai Key Laboratory for Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
E-mail: gxjin@fudan.edu.cn
Fax: +86-21-65641740
Tel: +86-21-65643776

Abstract

Novel half-sandwich metal (Ir, Rh) complexes constructed from carboranylthioamide ligands containing an unexpected metal–boron bond were synthesized and characterized. The strong base n-butyllithium is demonstrated to be necessary in the reaction process.

Graphical abstract: Metal-induced B–H bond activation: reactions between half-sandwich Ir and Rh complexes with carboranylthioamide

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4DT03624G
Article type
Communication
Submitted
26 Nov 2014
Accepted
28 Nov 2014
First published
28 Nov 2014

Dalton Trans., 2015,44, 1530-1533

Author version available

Download author version (PDF)

Permissions

Request permissions

Metal-induced B–H bond activation: reactions between half-sandwich Ir and Rh complexes with carboranylthioamide

B. Xu, Y. Wang, Z. Yao and G. Jin, Dalton Trans., 2015, 44, 1530 DOI: 10.1039/C4DT03624G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements