Two novel 3d–4f heterometallic coordination polymers with infinite [Ln4(OH)4]n8n+ chains involving in situ decarboxylation

Wen-Ya Wu; Rui-Feng Zhang; Xue-Jing Zhang; Peng Cheng

doi:10.1039/C5DT00586H

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Two novel 3d–4f heterometallic coordination polymers with infinite [Ln₄(OH)₄]_n⁸ⁿ⁺ chains involving in situ decarboxylation†

Wen-Ya Wu,^a Rui-Feng Zhang,*^a Xue-Jing Zhang^b and Peng Cheng*^b

Author affiliations

* Corresponding authors

^a School of Chemistry & Material Science, Shanxi Normal University, Linfen, Shanxi 041000, China
E-mail: nkzrf@163.com

^b Department of Chemistry, Key Laboratory of Advanced Energy Material Chemistry, MOE, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Abstract

Two unique heterometallic {Ln₄Co} coordination polymers with infinite Ln₄(OH)₄]_n⁸ⁿ⁺ chains have been successfully assembled, which represent the first example of heterometallic Ln–Co coordination polymers containing infinite lanthanide hydroxide chains.

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Article information

DOI: https://doi.org/10.1039/C5DT00586H
Article type: Communication
Submitted: 09 Feb 2015
Accepted: 19 Mar 2015
First published: 23 Mar 2015

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Dalton Trans., 2015,44, 7144-7147

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Two novel 3d–4f heterometallic coordination polymers with infinite [Ln₄(OH)₄]_n⁸ⁿ⁺ chains involving in situ decarboxylation

W. Wu, R. Zhang, X. Zhang and P. Cheng, Dalton Trans., 2015, 44, 7144 DOI: 10.1039/C5DT00586H

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