Issue 16, 2015
From the journal:

Dalton Transactions

A tetranuclear arylstibonic acid with an adamantane type structure†‡

Julian Brünig,a   Emanuel Hupf,a   Enno Lork,a   Stefan Mebs*b  and  Jens Beckmann*a  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Bremen, Leobener Straße, 28359 Bremen, Germany
E-mail: j.beckmann@uni-bremen.de

b Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany
E-mail: stefan.mebs@fu-berlin.de

Abstract

Oxidative chlorination of ArSbCl2 (1) with SO2Cl2 provided ArSbCl4 (2), the base hydrolysis of which gave rise to the arylstibonic acid (ArSb)4O6(OH)4 (3) having an adamantane type structure. The intramolecularly coordinating substituent Ar = 6-diphenylphosphinoacenaphth-5-yl- modulates the Lewis acidity of 1–3 and prevents extensive aggregation.

Graphical abstract: A tetranuclear arylstibonic acid with an adamantane type structure

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Article information

DOI
https://doi.org/10.1039/C5DT00588D
Article type
Communication
Submitted
09 Feb 2015
Accepted
09 Mar 2015
First published
12 Mar 2015

Dalton Trans., 2015,44, 7105-7108

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A tetranuclear arylstibonic acid with an adamantane type structure

J. Brünig, E. Hupf, E. Lork, S. Mebs and J. Beckmann, Dalton Trans., 2015, 44, 7105 DOI: 10.1039/C5DT00588D

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