A TpyRu2+-based bismetallopolymer and its performance in catalytic water oxidation (Tpy = 4-(p-methoxyphenyl)-2,2′:6′,2′′-terpyridine)

Die Liu; Qianqian Liu; Yiming Li; Meng Wang; Xiaoyu Yang; Tun Wu; Charles Moorefield; Pingshan Wang; George R. Newkome

doi:10.1039/C5DT01004G

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A TpyRu²⁺-based bismetallopolymer and its performance in catalytic water oxidation (Tpy = 4-(p-methoxyphenyl)-2,2′:6′,2′′-terpyridine)†

Die Liu,‡^a Qianqian Liu,‡^a Yiming Li,^a Meng Wang,^a Xiaoyu Yang,^a Tun Wu,^a Charles Moorefield,^b Pingshan Wang*^a and George R. Newkome*^b

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* Corresponding authors

^a College of chemistry and chemical engineering, Central south university, Changsha 410083, China
E-mail: chemwps@csu.edu.cn
Fax: +86-731 888796161

^b Departments of Polymer Science, Maurice Morton Institute of Polymer Science, and Chemistry. The University of Akron, Akron, OH 44325-4717, USA
E-mail: newkome@uakron.edu
Fax: +1 330 972 2413
Tel: +1 330 972 6458

Abstract

A bismetallo-organic polymer was successfully prepared by treating a metallo-ligand with Ag⁺; characterization was accomplished by NMR, UV-vis, and single crystal X-ray analyses. This heteronuclear polymer achieved more than a two-fold turnover number (TON) and a faster reaction rate in comparison to a Ce-driven Ru-monomer in catalytic water oxidation.

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Article information

DOI: https://doi.org/10.1039/C5DT01004G
Article type: Communication
Submitted: 12 Mar 2015
Accepted: 19 May 2015
First published: 19 May 2015

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Dalton Trans., 2015,44, 11269-11273

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A TpyRu²⁺-based bismetallopolymer and its performance in catalytic water oxidation (Tpy = 4-(p-methoxyphenyl)-2,2′:6′,2′′-terpyridine)

D. Liu, Q. Liu, Y. Li, M. Wang, X. Yang, T. Wu, C. Moorefield, P. Wang and G. R. Newkome, Dalton Trans., 2015, 44, 11269 DOI: 10.1039/C5DT01004G

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