Issue 19, 2015

Sequential electrophilic P–C bond formation in metal-coordinated chlorophosphines

Abstract

In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with unsaturated organic substrates, leading to P–C bond formation. This methodology can be applied sequentially two or three times, stepwise or in one-pot reactions, to form phosphines with three different substituents. The reactions are rapid and high-yielding, and can be applied to a wide range of organic substrates, making them valuable tools for P–C bond formation.

Graphical abstract: Sequential electrophilic P–C bond formation in metal-coordinated chlorophosphines

Supplementary files

Article information

Article type
Communication
Submitted
02 Apr 2015
Accepted
08 Apr 2015
First published
08 Apr 2015

Dalton Trans., 2015,44, 8788-8791

Author version available

Sequential electrophilic P–C bond formation in metal-coordinated chlorophosphines

A. Jayaraman, T. V. Jacob, J. Bisskey and B. T. Sterenberg, Dalton Trans., 2015, 44, 8788 DOI: 10.1039/C5DT01281C

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