Dodecanuclear [MnIII6LnIII6] species: synthesis, structures and characterization of magnetic relaxation phenomena

Thomais G. Tziotzi; Demetrios I. Tzimopoulos; Tadeusz Lis; Ross Inglis; Constantinos J. Milios

doi:10.1039/C5DT01695A

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Dodecanuclear [Mn ^III₆Ln ^III₆] species: synthesis, structures and characterization of magnetic relaxation phenomena†

Thomais G. Tziotzi,^a Demetrios I. Tzimopoulos,^b Tadeusz Lis,^c Ross Inglis*^d and Constantinos J. Milios*^a

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* Corresponding authors

^a Department Of Chemistry, University of Crete, Voutes 71003, Herakleion, Greece
E-mail: komil@chemistry.uoc.gr
Fax: +30-2810-545001
Tel: +30-2810-545099

^b Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, Greece

^c Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland

^d School of Chemistry, The University of Edinburgh, David Brewster Road, EH9 3FJ, Edinburgh, UK
E-mail: ringlis@staffmail.ed.ac.uk

Abstract

The use of H₃L (= 2-(β-naphthalideneamino)-2-hydroxymethyl-1-propanol) in mixed-metal manganese–lanthanide carboxylate cluster chemistry has led to the isolation of two new dodecametallic heteronuclear isostructural [Mn^III₆Ln^III₆] complexes (Ln = Gd, Dy), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals suggesting possible single molecule magnetism behaviour.

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Article information

DOI: https://doi.org/10.1039/C5DT01695A
Article type: Communication
Submitted: 05 May 2015
Accepted: 02 Jun 2015
First published: 02 Jun 2015

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Dalton Trans., 2015,44, 11696-11699

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Dodecanuclear [Mn^III₆Ln^III₆] species: synthesis, structures and characterization of magnetic relaxation phenomena

T. G. Tziotzi, D. I. Tzimopoulos, T. Lis, R. Inglis and C. J. Milios, Dalton Trans., 2015, 44, 11696 DOI: 10.1039/C5DT01695A

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