Syntheses, structures, and 1H, 13C{1H} and 119Sn{1H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds

Abstract

The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (¹H, ¹³C{¹H} and ¹¹⁹Sn{¹H}), for a series of Me₃SnX (X = O-2,6-^tBu₂C₆H₃ (1), (Me₃Sn)N(2,6-ⁱPr₂C₆H₃) (3), NH-2,4,6-^tBu₃C₆H₂ (4), N(SiMe₃)₂ (5), NEt₂, C₅Me₅ (6), Cl, Br, I, and SnMe₃) compounds in benzene-d₆, toluene-d₈, dichloromethane-d₂, chloroform-d₁, acetonitrile-d₃, and tetrahydrofuran-d₈ are reported. The X-ray crystal structures of Me₃Sn(O-2,6-^tBu₂C₆H₃) (1), Me₃Sn(O-2,6-ⁱPr₂C₆H₃) (2), and (Me₃Sn)(NH-2,4,6-^tBu₃C₆H₂) (4) are also presented. These compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.