Well-defined palladium(II) complexes for ligand-enabled C(sp3)-alkynylation

Vinod G. Landge; Manoj K. Sahoo; Siba P. Midya; Garima Jaiswal; Ekambaram Balaraman

doi:10.1039/C5DT02772A

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Well-defined palladium(ii) complexes for ligand-enabled C(sp³)-alkynylation†

Vinod G. Landge,^ab Manoj K. Sahoo,^ab Siba P. Midya,^ab Garima Jaiswal^ab and Ekambaram Balaraman*^ab

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* Corresponding authors

^a Catalysis Division, Dr. Homi Bhabha Road, CSIR-National Chemical Laboratory (CSIR-NCL), Pune 411008, India
E-mail: eb.raman@ncl.res.in, balaramane2002@yahoo.com

^b Academy of Scientific and Innovative Research (AcSIR), New Delhi 110025, India

Abstract

The first example of ligand-enabled C(sp³)-alkynylation of 8-methylquinoline is reported. The reaction is catalysed by well-defined Pd(II) complexes. The present C(sp³)-alkynylation has a broad substrate scope as well as functional group tolerance and proceeds efficiently under mild conditions.

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Article information

DOI: https://doi.org/10.1039/C5DT02772A
Article type: Communication
Submitted: 27 May 2015
Accepted: 22 Jul 2015
First published: 22 Jul 2015

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Dalton Trans., 2015,44, 15382-15386

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Well-defined palladium(II) complexes for ligand-enabled C(sp³)-alkynylation

V. G. Landge, M. K. Sahoo, S. P. Midya, G. Jaiswal and E. Balaraman, Dalton Trans., 2015, 44, 15382 DOI: 10.1039/C5DT02772A

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