Issue 48, 2015
From the journal:

Dalton Transactions

Gallium(iii)corrole–BODIPY hybrid: novel photophysical properties and first observation of B–F⋯F interactions†

Biju Basumatary,a   R. V. Ramana Reddy,a   Subhrajyoti Bhandarya  and  Jeyaraman Sankar*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Indore Bypass Road, Bhopal, India
E-mail: sankar@iiserb.ac.in
Fax: +91-755-6692392
Tel: +91-755-6692-334

Abstract

Anchoring a BODIPY onto Ga(III)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound 4 hosts the first example of a novel B–F⋯F interaction as well.

Graphical abstract: Gallium(iii)corrole–BODIPY hybrid: novel photophysical properties and first observation of B–F⋯F interactions

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Article information

DOI
https://doi.org/10.1039/C5DT03104D
Article type
Communication
Submitted
11 Aug 2015
Accepted
05 Nov 2015
First published
05 Nov 2015

Dalton Trans., 2015,44, 20817-20821

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Gallium(III)corrole–BODIPY hybrid: novel photophysical properties and first observation of B–F⋯F interactions

B. Basumatary, R. V. Ramana Reddy, S. Bhandary and J. Sankar, Dalton Trans., 2015, 44, 20817 DOI: 10.1039/C5DT03104D

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