Single molecule magnet behavior observed in a 1-D dysprosium chain with quasi-D5h symmetry

Xing-Cai Huang; Ming Zhang; Dayu Wu; Dong Shao; Xin-Hua Zhao; Wei Huang; Xin-Yi Wang

doi:10.1039/C5DT04147C

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Single molecule magnet behavior observed in a 1-D dysprosium chain with quasi-D_5h symmetry†

Xing-Cai Huang,^ab Ming Zhang,^a Dayu Wu,*^a Dong Shao,^b Xin-Hua Zhao,^b Wei Huang^a and Xin-Yi Wang*^b

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* Corresponding authors

^a Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Collaborative Innovation Center of Advanced Catalysis & Green Manufacturing, School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, China
E-mail: wudy@cczu.edu.cn

^b State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China
E-mail: wangxy66@nju.edu.cn

Abstract

Two one-dimensional (1-D) chain complexes with pentagonal bipyramidal Dy^III centers have been synthesized and magnetically characterized. Field-induced single molecule magnet behavior has been revealed in both compounds, which is still rarely reported in a lanthanide compound with a pentagonal bipyramidal coordination geometry. Their crystal field parameters and orientations of the magnetic easy axes were obtained from the simulation of the magnetic data and the electrostatic model calculation.

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Article information

DOI: https://doi.org/10.1039/C5DT04147C
Article type: Communication
Submitted: 22 Oct 2015
Accepted: 11 Nov 2015
First published: 11 Nov 2015

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Dalton Trans., 2015,44, 20834-20838

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Single molecule magnet behavior observed in a 1-D dysprosium chain with quasi-D_5h symmetry

X. Huang, M. Zhang, D. Wu, D. Shao, X. Zhao, W. Huang and X. Wang, Dalton Trans., 2015, 44, 20834 DOI: 10.1039/C5DT04147C

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