Issue 5, 2015
From the journal:

Green Chemistry

Facile synthesis of (E)-β-nitroolefinic alkoxyamines via silver-catalyzed decarboxylative nitroaminoxylation of phenylpropiolic acids†

Hong Yan,a   Jincheng Mao,*ab   Guangwei Rong,a   Defu Liu,a   Yang Zhenga  and  Yue Hea  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

b State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, P. R. China
E-mail: jcmao@suda.edu.cn
Fax: (+86)512-6588-0403

Abstract

A novel silver-catalyzed decarboxylative nitroaminoxylation reaction of phenylpropiolic acids is described, leading to (E)-β-nitroolefinic alkoxyamines. The catalyst loading could be decreased to as low as 1 mol%, whilst still showing good efficiency.

Graphical abstract: Facile synthesis of (E)-β-nitroolefinic alkoxyamines via silver-catalyzed decarboxylative nitroaminoxylation of phenylpropiolic acids

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Article information

DOI
https://doi.org/10.1039/C5GC00302D
Article type
Communication
Submitted
08 Feb 2015
Accepted
04 Mar 2015
First published
04 Mar 2015

Green Chem., 2015,17, 2723-2726

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Facile synthesis of (E)-β-nitroolefinic alkoxyamines via silver-catalyzed decarboxylative nitroaminoxylation of phenylpropiolic acids

H. Yan, J. Mao, G. Rong, D. Liu, Y. Zheng and Y. He, Green Chem., 2015, 17, 2723 DOI: 10.1039/C5GC00302D

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