Issue 10, 2015

I/TBHP catalyzed Csp3–N/Csp2–N bond formation via oxidative coupling with benzophenone imine in water

Abstract

An I/TBHP catalyzed oxidative amination with benzophenone imine under environmentally benign conditions was developed. A wide range of substrates underwent oxidative amination with benzophenone imine to afford the corresponding primary amine and amide products in good yields. The active iodine species were identified by well-designed control experiments for elucidating the mechanism.

Graphical abstract: I−/TBHP catalyzed Csp3–N/Csp2–N bond formation via oxidative coupling with benzophenone imine in water

Supplementary files

Article information

Article type
Communication
Submitted
17 May 2015
Accepted
11 Aug 2015
First published
12 Aug 2015

Green Chem., 2015,17, 4715-4719

I/TBHP catalyzed Csp3–N/Csp2–N bond formation via oxidative coupling with benzophenone imine in water

H. Huang, W. Chen, Y. Xu and J. Li, Green Chem., 2015, 17, 4715 DOI: 10.1039/C5GC01056J

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