Synthesis of 17-membered azalides from a 16-membered macrolide utilizing amide-selective silane reduction†
Abstract
The synthesis of 17-membered azalides was achieved using the following key steps: (i)
* Corresponding authors
a
Institute of Microbial Chemistry (BIKAKEN), Hiyoshi, 3-34-17 Ida, Nakahara-ku, Kawasaki-shi, Kanagawa 211-0035, Japan
E-mail:
aseki@bikaken.or.jp
Fax: +81 44 755 3099
b Institute of Microbial Chemistry (BIKAKEN), Tokyo, 3-14-23 Kamiosaki, Shinagawa-ku, Tokyo 141-0021, Japan
The synthesis of 17-membered azalides was achieved using the following key steps: (i)
A. Seki, T. Mori, K. Sasaki, Y. Takahashi, T. Miyake and Y. Akamatsu, Med. Chem. Commun., 2015, 6, 581 DOI: 10.1039/C4MD00489B
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