One-pot syntheses of surface functionalized germanium nanocrystals (GeNCs) based upon traditional hot injection and microwave-assisted heating of a Ge(II) dihydride single source precursor have been developed. The reported procedures offer in situ hydrogermylation-based covalent attachment of alkene/alkyne derived surface moieties that give access to hydrophobic or hydrophilic GeNCs.
T. K. Purkait, A. K. Swarnakar, G. B. De Los Reyes, F. A. Hegmann, E. Rivard and J. G. C. Veinot, Nanoscale, 2015, 7, 2241 DOI: 10.1039/C4NR05125D
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