Isolation and structure elucidation of six new divergolides reveal unusual ansamycin diversification reactions including formation of the unusual isobutenyl side chain from a branched polyketide synthase extender unit, azepinone ring closure, macrolide ring contraction and formation of a seco variant by a neighboring group-assisted decarboxylation.
L. Ding, J. Franke and C. Hertweck, Org. Biomol. Chem., 2015, 13, 1618 DOI: 10.1039/C4OB02244K
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