Issue 25, 2015

meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

Abstract

Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels–Alder reaction. The basic optical properties of the prepared new anthraquinonoporphyrin and its complexes with Zn and Pd were studied.

Graphical abstract: meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

Supplementary files

Article information

Article type
Paper
Submitted
01 May 2015
Accepted
14 May 2015
First published
14 May 2015
This article is Open Access
Creative Commons BY license

Org. Biomol. Chem., 2015,13, 6977-6983

Author version available

meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

M. A. Filatov, E. Heinrich, K. Landfester and S. Baluschev, Org. Biomol. Chem., 2015, 13, 6977 DOI: 10.1039/C5OB00884K

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