Issue 3, 2015

8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

Abstract

Cycloalkyl-modified 8-arylimino-5,6,7-trihydroquinolylnickel pre-catalysts, activated with either MAO or Et2AlCl, are highly active for the polymerization of ethylene into branched polyethylene waxes with narrow polydispersity.

Graphical abstract: 8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

Supplementary files

Article information

Article type
Research Article
Submitted
15 Oct 2014
Accepted
08 Jan 2015
First published
12 Jan 2015

Inorg. Chem. Front., 2015,2, 223-227

Author version available

8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

Z. Sun, E. Yue, M. Qu, I. V. Oleynik, I. I. Oleynik, K. Li, T. Liang, W. Zhang and W. Sun, Inorg. Chem. Front., 2015, 2, 223 DOI: 10.1039/C4QI00162A

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