Issue 7, 2015

Palladium catalyzed amide-oxazoline directed C–H acetoxylation of arenes

Abstract

Herein we reported a Pd-catalyzed ortho-acetoxylation of arenes through a six-membered system using an amide-oxazoline as the directing group. A wide range of aryls and heteroaryls are tolerated. The approach provides general and straightforward access to phenol esters without the need for extra oxidants.

Graphical abstract: Palladium catalyzed amide-oxazoline directed C–H acetoxylation of arenes

Associated articles

Supplementary files

Article information

Article type
Research Article
Submitted
31 Mar 2015
Accepted
28 Apr 2015
First published
29 Apr 2015

Org. Chem. Front., 2015,2, 797-800

Palladium catalyzed amide-oxazoline directed C–H acetoxylation of arenes

B. Liu, X. Huang, X. Wang, Z. Ge and R. Li, Org. Chem. Front., 2015, 2, 797 DOI: 10.1039/C5QO00104H

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