Structural and magnetic properties of tetragonal perovskite BaFe1−xBixO3−δ

Muhammad Asim Farid; Hao Zhang; Xiaohuan Lin; Aimei Yang; Sihai Yang; Guobao Li; Fuhui Liao; Jianhua Lin

doi:10.1039/C4RA13540G

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Structural and magnetic properties of tetragonal perovskite BaFe_1−xBi_xO_3−δ†

Muhammad Asim Farid,^a Hao Zhang,^a Xiaohuan Lin,^a Aimei Yang,^b Sihai Yang,^c Guobao Li,*^a Fuhui Liao^a and Jianhua Lin*^a

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R. China
E-mail: liguobao@pku.edu.cn
Fax: +86-10-6275-3541

^b A College of Materials and Engineering, Institution Guangxi Guilin University of Technology, Guilin 541004, China

^c School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK

Abstract

A series of BaFe_1−xBi_xO_3−δ (0.09 ≤ x ≤ 0.35) has been synthesized by a traditional solid state method. They all crystallize in space group P4/mmm (with a = 4.0759(1) Å, c = 4.0782(1) Å for x = 0.15) confirmed by the combinational use of powder X-ray, synchrotron, neutron, and electron diffractions. The magnetic susceptibility measurements show that the antiferromagnetic transition for these materials occurs from 64 to 50 K.

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Article information

DOI: https://doi.org/10.1039/C4RA13540G
Article type: Paper
Submitted: 31 Oct 2014
Accepted: 09 Jan 2015
First published: 09 Jan 2015

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RSC Adv., 2015,5, 12866-12871

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Structural and magnetic properties of tetragonal perovskite BaFe_1−xBi_xO_3−δ

M. A. Farid, H. Zhang, X. Lin, A. Yang, S. Yang, G. Li, F. Liao and J. Lin, RSC Adv., 2015, 5, 12866 DOI: 10.1039/C4RA13540G

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