Reductive amination using a combination of CaH2 and noble metal

Carole Guyon; Eric Da Silva; Romain Lafon; Estelle Métay; Marc Lemaire

doi:10.1039/C4RA14808H

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Reductive amination using a combination of CaH₂ and noble metal†

Carole Guyon,‡^a Eric Da Silva,^a Romain Lafon,^a Estelle Métay*^a and Marc Lemaire*^a

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* Corresponding authors

^a Equipe Catalyse Synthèse Environnement, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, UMR-CNRS 5246, Université de Lyon, Université Claude Bernard-Lyon 1, Bâtiment Curien, 43 boulevard du 11 Novembre 1918, F-69622 Villeurbanne Cedex, France
E-mail: estelle.metay@univ-lyon1.fr, marc.lemaire.chimie@univ-lyon1.fr
Fax: +33 (0)4 72 43 14 08
Tel: +33 (0)4 72 44 85 07, +33 (0)4 72 43 14 07

Abstract

Amines were prepared by a reductive amination reaction in the presence of calcium hydride and Pt/C. The in situ formation of water seems to be the key to activate CaH₂ to reduce the intermediate imine.

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Article information

DOI: https://doi.org/10.1039/C4RA14808H
Article type: Communication
Submitted: 18 Nov 2014
Accepted: 28 Nov 2014
First published: 28 Nov 2014

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RSC Adv., 2015,5, 2292-2298

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Reductive amination using a combination of CaH₂ and noble metal

C. Guyon, E. Da Silva, R. Lafon, E. Métay and M. Lemaire, RSC Adv., 2015, 5, 2292 DOI: 10.1039/C4RA14808H

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