Squashed {Fe2IIIM4III} octahedra (M = Y, Gd, Dy) from the first use of the cyanoacetate ligand in 3d/4f coordination chemistry

Christina D. Polyzou; Amer Baniodeh; Nicola Magnani; Valeriu Mereacre; Nicolas Zill; Christopher E. Anson; Spyros P. Perlepes; Annie K. Powell

doi:10.1039/C4RA15458D

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Squashed {Fe₂^IIIM₄^III} octahedra (M = Y, Gd, Dy) from the first use of the cyanoacetate ligand in 3d/4f coordination chemistry†

Christina D. Polyzou,^ab Amer Baniodeh,^bc Nicola Magnani,^c Valeriu Mereacre,^b Nicolas Zill,^c Christopher E. Anson,^b Spyros P. Perlepes*^a and Annie K. Powell*^bc

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Patras, 26504 Patras, Greece
E-mail: perlepes@patreas.upatras.gr
Tel: +30 2610 996730

^b Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany
E-mail: annie.powell@kit.edu
Tel: +49 721 60842135

^c Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

The first use of the cyanoacetate ligand in 3d/4f-metal chemistry leads to {Fe₂^IIIM₄^III} (M = Dy, Gd, Y) coordination clusters with a squashed octahedral core structure unprecedented in Fe/4f compounds; the Dy^III compound exhibits slow relaxation of the magnetisation.

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Article information

DOI: https://doi.org/10.1039/C4RA15458D
Article type: Communication
Submitted: 28 Nov 2014
Accepted: 06 Jan 2015
First published: 06 Jan 2015

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RSC Adv., 2015,5, 10763-10767

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Squashed {Fe₂^IIIM₄^III} octahedra (M = Y, Gd, Dy) from the first use of the cyanoacetate ligand in 3d/4f coordination chemistry

C. D. Polyzou, A. Baniodeh, N. Magnani, V. Mereacre, N. Zill, C. E. Anson, S. P. Perlepes and A. K. Powell, RSC Adv., 2015, 5, 10763 DOI: 10.1039/C4RA15458D

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