Issue 29, 2015
From the journal:

RSC Advances

Synthesis of highly dispersed cobalt catalyst for hydroformylation of 1-hexene†

Bin Wang,a   Jian-Feng Chena  and  Yi Zhang*a  

* Corresponding authors

a State Key Laboratory of Organic–Inorganic Composites, Research Centre of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China
E-mail: yizhang@mail.buct.edu.cn
Fax: +86 10 64423474
Tel: +86 10 64447274

Abstract

Highly dispersed Co/SiO2 catalysts were prepared using an ethylene glycol (EG) modified silica support. The modified SiO2 support significantly promoted the dispersion of supported cobalt and adding a small amount of Ru increased the reducibility of the highly dispersed cobalt oxide. The Co–Ru/SiO2 (EG) catalyst exhibited 3 times higher 1-hexene conversion and 18 times higher heptanal yield than the conventional Co/SiO2 catalyst.

Graphical abstract: Synthesis of highly dispersed cobalt catalyst for hydroformylation of 1-hexene

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Article information

DOI
https://doi.org/10.1039/C4RA17035K
Article type
Communication
Submitted
25 Dec 2014
Accepted
11 Feb 2015
First published
11 Feb 2015

RSC Adv., 2015,5, 22300-22304

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Synthesis of highly dispersed cobalt catalyst for hydroformylation of 1-hexene

B. Wang, J. Chen and Y. Zhang, RSC Adv., 2015, 5, 22300 DOI: 10.1039/C4RA17035K

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