Issue 32, 2015
From the journal:

RSC Advances

Synthesis of ferrocene-containing six-membered cyclic ureas via α-ferrocenyl carbocations†

Aleksandra Minić,a   Dragana Stevanović,a   Ivan Damljanović,a   Anka Pejović,a   Mirjana Vukićević,b   Goran A. Bogdanović,c   Niko S. Radulovićd  and  Rastko D. Vukićević*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, University of Kragujevac, R. Domanovića 12, 34000 Kragujevac, Serbia
E-mail: vuk@kg.ac.rs
Fax: +381 34 335040
Tel: +381 34 300268

b Department of Pharmacy, Faculty of Medicinal Sciences, University of Kragujevac, S. Markovića 69, 34000 Kragujevac, Serbia

c Vinča Institute of Nuclear Sciences, University of Belgrade, PO Box 522, 11001 Belgrade, Serbia

d Department of Chemistry, Faculty of Science and Mathematics, University of Niš, Višegradska 33, 18000 Niš, Serbia

Abstract

A series of ferrocene-containing six-membered cyclic ureas (1-aryl-4-ferrocenyl-3-phenyltetrahydropyrimidin-2(1H)-ones) was synthesized (in high-to-excellent yields) by reacting the corresponding aminopropanols with phenyl isocyanate and the subsequent intramolecular cyclization of the thus obtained β-hydroxy ureas (prompted by acetic acid), via an α-ferrocenyl carbocation.

Graphical abstract: Synthesis of ferrocene-containing six-membered cyclic ureas via α-ferrocenyl carbocations

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Article information

DOI
https://doi.org/10.1039/C5RA01383F
Article type
Communication
Submitted
23 Jan 2015
Accepted
02 Mar 2015
First published
03 Mar 2015

RSC Adv., 2015,5, 24915-24919

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Synthesis of ferrocene-containing six-membered cyclic ureas via α-ferrocenyl carbocations

A. Minić, D. Stevanović, I. Damljanović, A. Pejović, M. Vukićević, G. A. Bogdanović, N. S. Radulović and R. D. Vukićević, RSC Adv., 2015, 5, 24915 DOI: 10.1039/C5RA01383F

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