Issue 27, 2015
From the journal:

RSC Advances

Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis†

Tatsuya Chinzei,a   Kazuki Miyazawa,a   Yusuke Yasu,a   Takashi Koike*a  and  Munetaka Akita*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
E-mail: koike.t.ad@m.titech.ac.jp, makita@res.titech.ac.jp
Fax: +81-45-924-5230
Tel: +81-45-924-5230

Abstract

A simple generation method of carbon radicals via 1e-oxidation of organotrifluoroborates and carboxylic acids by the action of an organophotoredox catalyst, 9-mesityl-10-methylacridinium perchlorate ([Acr+–Mes]ClO4), has been developed. This organophotocatalytic protocol is amenable to radical C–C bond formation with electron-deficient olefins.

Graphical abstract: Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis

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Article information

DOI
https://doi.org/10.1039/C5RA01826A
Article type
Communication
Submitted
10 Dec 2014
Accepted
12 Feb 2015
First published
13 Feb 2015

RSC Adv., 2015,5, 21297-21300

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Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis

T. Chinzei, K. Miyazawa, Y. Yasu, T. Koike and M. Akita, RSC Adv., 2015, 5, 21297 DOI: 10.1039/C5RA01826A

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