Issue 45, 2015
From the journal:

RSC Advances

The siliconyl, boronyl, and iminoboryl ligands as analogues of the well-known carbonyl ligand: predicted reactivity towards dipolar cyclooligomerization in iron/cobalt carbonyl complexes†

Zhong Zhang,*ab   Liang Pu,a   Qianshu Lib  and  R. Bruce King*c  

* Corresponding authors

a College of Science, Northwest A&F University, Yangling, Shanxi 712100, P. R. China
E-mail: zhangzhong6@126.com
Fax: +86-29-87092226
Tel: +86-29-87092226

b Center for Computational Quantum Chemistry, South China Normal University, Guangzhou 510631, P. R. China

c Department of Chemistry and Center for Computational Chemistry, University of Georgia, Athens, Georgia 30602, USA
E-mail: rbking@uga.edu
Fax: +1-706-542-9454
Tel: +1-706-542-1901

Abstract

The Fe(CO)4(SiO), Co(CO)4(BO), and Co(CO)4(BNSiMe3) complexes analogous to the well-known Fe(CO)5 are predicted by density functional theory to undergo exothermic oligomerization to give the oligomers [Fe(CO)4]n(SinOn), [Co(CO)4]n(BnOn), and [Co(CO)4]2(B2N2Si2Me6) containing SinOn/BnOn/B2N2 rings with single bonds.

Graphical abstract: The siliconyl, boronyl, and iminoboryl ligands as analogues of the well-known carbonyl ligand: predicted reactivity towards dipolar cyclooligomerization in iron/cobalt carbonyl complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5RA01903F
Article type
Paper
Submitted
30 Jan 2015
Accepted
09 Apr 2015
First published
09 Apr 2015

RSC Adv., 2015,5, 35558-35563

Author version available

Download author version (PDF)

Permissions

Request permissions

The siliconyl, boronyl, and iminoboryl ligands as analogues of the well-known carbonyl ligand: predicted reactivity towards dipolar cyclooligomerization in iron/cobalt carbonyl complexes

Z. Zhang, L. Pu, Q. Li and R. B. King, RSC Adv., 2015, 5, 35558 DOI: 10.1039/C5RA01903F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements