Issue 45, 2015
From the journal:

RSC Advances

First total synthesis of cryptopyranmoscatone A2 from d-ribose†

A. Maheswara Reddy,a   Gowravaram Sabitha*a  and  Sirisha katukurib  

* Corresponding authors

a Natural Products Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad, A.P. 500 007, India
E-mail: gowravaramsr@yahoo.com, sabitha@iict.res.in
Fax: +91-40-27160512

b Nuclear Magnetic Resonance Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India

Abstract

The first total synthesis of a naturally occurring styryl lactone, cryptopyranmoscatone A2 has been achieved from inexpensive and highly abundant D-ribose. The key features of the synthetic strategy are the utilization of oxa-Michael addition, asymmetric allylation and metathesis reactions.

Graphical abstract: First total synthesis of cryptopyranmoscatone A2 from d-ribose

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Article information

DOI
https://doi.org/10.1039/C5RA03706A
Article type
Communication
Submitted
02 Mar 2015
Accepted
09 Apr 2015
First published
09 Apr 2015

RSC Adv., 2015,5, 35746-35752

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First total synthesis of cryptopyranmoscatone A2 from D-ribose

A. Maheswara Reddy, G. Sabitha and S. katukuri, RSC Adv., 2015, 5, 35746 DOI: 10.1039/C5RA03706A

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