Re2O7 catalyzed dienone-phenol rearrangement

Zilei Xia; Jiadong Hu; Zhigao Shen; Qizheng Yao; Weiqing Xie

doi:10.1039/C5RA04931H

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Re₂O₇ catalyzed dienone-phenol rearrangement†

Zilei Xia,‡^ab Jiadong Hu,‡^ab Zhigao Shen,^ab Qizheng Yao*^a and Weiqing Xie*^bc

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* Corresponding authors

^a Department of Medicinal Chemistry & State Key Laboratory of Natural Medicines, Center of Drug Discovery, China Pharmaceutical University, 24 Tongjiaxiang, Nanjing 210009, China
E-mail: qz_yao@aliyun.com

^b Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Science, Northwest A&F University, 22 Xiong Road, Yangling 712100, Shaanxi, China
E-mail: xiewq@sioc.ac.cn

^c State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

The dienone-phenol rearrangement of 4,4-disubstituted cyclohexadienones catalyzed by Re₂O₇ has been described. Multi-substituted phenols can be efficiently obtained in good to excellent yields by employing this catalytic protocol.

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Article information

DOI: https://doi.org/10.1039/C5RA04931H
Article type: Communication
Submitted: 20 Mar 2015
Accepted: 13 Apr 2015
First published: 13 Apr 2015

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RSC Adv., 2015,5, 38499-38502

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Re₂O₇ catalyzed dienone-phenol rearrangement

Z. Xia, J. Hu, Z. Shen, Q. Yao and W. Xie, RSC Adv., 2015, 5, 38499 DOI: 10.1039/C5RA04931H

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