Issue 128, 2015
From the journal:

RSC Advances

CPL emission of chiral BINOL-based polymers via chiral transfer of the conjugated chain backbone structure†

Fei Li,a   Yuxiang Wang,a   Yuan Sheng,a   Guo Wei,a   Yixiang Cheng*a  and  Chengjian Zhu*a  

* Corresponding authors

a Key Lab of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China
E-mail: yxcheng@nju.edu.cn, cjzhu@nju.edu.cn
Tel: +86-25-89686508

Abstract

Two chiral BINOL-based polymer enantiomers R-P and S-P incorporating phenothiazine moieties in the main chain backbone can exhibit mirror image Cotton effects and emit green color circularly polarized luminescence (CPL), which can be attributed to chiral transfer of binaphthyl to chromophore phenothiazine moieties via the conjugated polymer chain backbone.

Graphical abstract: CPL emission of chiral BINOL-based polymers via chiral transfer of the conjugated chain backbone structure

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Article information

DOI
https://doi.org/10.1039/C5RA23329A
Article type
Communication
Submitted
05 Nov 2015
Accepted
01 Dec 2015
First published
03 Dec 2015

RSC Adv., 2015,5, 105851-105854

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CPL emission of chiral BINOL-based polymers via chiral transfer of the conjugated chain backbone structure

F. Li, Y. Wang, Y. Sheng, G. Wei, Y. Cheng and C. Zhu, RSC Adv., 2015, 5, 105851 DOI: 10.1039/C5RA23329A

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