Issue 4, 2015

Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system

Abstract

A simple, “click” synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P2N2 ring unit, with P atoms flanking the NCN fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifying the electronic and steric character of these carbenes.

Graphical abstract: Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system

Supplementary files

Article information

Article type
Edge Article
Submitted
21 Dec 2014
Accepted
13 Feb 2015
First published
13 Feb 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2015,6, 2506-2510

Author version available

Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system

T. Roth, V. Vasilenko, C. G. M. Benson, H. Wadepohl, D. S. Wright and L. H. Gade, Chem. Sci., 2015, 6, 2506 DOI: 10.1039/C4SC03966A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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